Rog Editition 10 Rampage 5 User Manual

EdititionRog
Hello guys, I have just upgraded my PC from 32 GB ram to 64 GB, now my PC will not boot from my M.2 SSD.
PC was running fine before installing the new ram, the ram kit is the same as the one that was fitted.
now I am getting a flashing light for the PCIE lane 4 ( nothing installed in lane 4)
Mem test OK
Q-Code 6d and BF
I can select boot override in the BIOS for the M.2 drive and the PC boots windows fine and everything works, PC won't boot again after restart.
Any Ideas on how to fix this?
System;
I7 5960x
Rampage V edition 10 - BIOS 1002
64GB G.Skill RipJaw IV 2800
RM1000i
HD7950 x2
Boot - samsung 950pro V-NAND SSD M.2
840 evo 250 GB SSD
1TB segate
Windows 10 Pro
Rampage

Rog Edition 10 Rampage 5 User Manual Sim Card

Rampage V Edition 10 isn’t just VR Ready — it goes way beyond! The ASUS ROG Beyond VR Ready marque means that Rampage V Edition 10 has been tested with loads of class-leading components to ensure that your productivity, gaming and entertainment needs are tuned for maximum performance after you’ve taken off the headset. Oct 14, 2016  JJ from ASUS along with Carey walkthrough the in’s and outs of overclocking your CPU and memory on ASUS X99 motherboards. Whether you are interested in understand how to manually overclock or go.

Asus Rog Rampage V Edition 10

Hey guys!!!
I have a question regarding ram quad channel ROG RAMPAGE V EDITION 10.
I have 5 sticks of DDR4 CMK16GX4M2B3000C15 RAM with 3000MHz + XMP profile ON .
How is 5 sticks give me quad channel ... ?
P.S. Look at attached files for more info about my system and BIOS
My system:
Processor (CPU)
CPU Name Intel® Core™ i7-6850K CPU @ 3.60GHz
Threading 1 CPU - 6 Core - 12 Threads
Frequency 4248.71 MHz (34 * 124.96 MHz) - Uncore: 3124 MHz
Multiplier Current: 34 / Min: 12 / Max: 38
Architecture Broadwell-E/EP / Stepping: M0 / Technology: 14 nm
CPUID / Ext. 6.F.1 / 6.4F
IA Extensions MMX, SSE, SSE2, SSE3, SSSE3, SSE4.1, SSE4.2, EM64T, VT-x, AES, AVX, AVX2, FMA3, TSX
Caches L1D : 32 KB / L2 : 256 KB / L3 : 15360 KB
Caches Assoc. L1D : 8-way / L2 : 8-way / L3 : 20-way
Microcode Rev. 0xB00001C ► Spectre (CVE-2017-5715) Vulnerable ◄
TDP / Vcore 140 Watts / 1.301 Volts
Temperature 61 °C / 142 °F
Type Retail (Stock Frequency : 3600 MHz)
Cores Frequencies #00: 4248.71 MHz #01: 4248.71 MHz #02: 4248.71 MHz #03: 4248.71 MHz 
#04: 4248.71 MHz #05: 4248.71 MHz 
Motherboard
Model Asus RAMPAGE V EDITION 10
Socket Socket 2011 LGA
North Bridge Intel Broadwell-E rev 01
South Bridge Intel X99 rev 05
BIOS American Megatrends Inc. 1801 (09/20/2017)
Memory (RAM)
Total Size 40960 MB
Type Quad Channel (256 bit) DDR4-SDRAM
Frequency 1374.6 MHz - Ratio 1:22
Timings 15-17-17-35-2 (tCAS-tRC-tRP-tRAS-tCR)
Slot #1 Module Corsair 8192 MB (DDR4-2137) - XMP 2.0 - P/N: CMK16GX4M2B3000C15
Slot #2 Module Corsair 8192 MB (DDR4-2137) - XMP 2.0 - P/N: CMK16GX4M2B3000C15
Slot #3 Module Corsair 8192 MB (DDR4-2137) - XMP 2.0 - P/N: CMK16GX4M2B3000C15
Slot #4 Module Corsair 8192 MB (DDR4-2137) - XMP 2.0 - P/N: CMK16GX4M2B3000C15
Slot #5 Module Corsair 8192 MB (DDR4-2137) - XMP 2.0 - P/N: CMK16GX4M2B3000C15
Graphic Card (GPU)
GPU Type NVIDIA GeForce GTX 1080 Ti (GP102) @ 139 MHz
GPU Brand EVGA Corp.
GPU Specs GP102-350 / Process: 16nm / Transistors: 12000M / Die Size: 471 mm² / TDP: 250W
GPU Units Shader Units: 3584 / Texture Units (TMU): 224 / Render Units (ROP): 88
GPU VRAM 11264 MB GDDR5X 352 bit @ 405 MHz
GPU APIs DirectX 12.0 (12_1) / OpenGL 4.5 / OpenCL 1.2 / Vulkan 1.0
Storage (HDD/SSD)
Model #1 Samsung SSD 850 PRO 1TB
Capacity #1 1024 GB
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